Picture of (R)-(+)-1,1′-Bi(2-naphthol), 99%

300828

(R)-(+)-1,1′-Bi(2-naphthol), 99%

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	5 g	$79.20

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Specifications
MSDS
COA
Product Documents
Safety

Products specifications

Common name	(R)-(+)-BINOL
Assay	99%
CAS #	18531-94-7
MDL #	MFCD00004068
Molecular Formula	C20H14O2
Molecular Weight	286.32
Beilstein	3616837.00
Reaxys-RN	997518.00
UN#	UN2811
Harmonized Tariff Code	2907.29
Appearance	white to off-white solid
Melting Point	208-210 °C
Density	1.30
[α]D	+36.0° (c=0.5, THF)
Reference	The (R)- and (S)-isomers are useful for the preparation of chiral reducing agents, crown ethers, organotitaniumreagents and hydroboration catalysts. For references, see Aldrichimica Acta, 16(1), 14 (1983). Catalytic asymmetric oxidation of sulfides to sulfoxides using R-(+)-binaphthol: N. Komatsu et al.; Tetrahedron Lett. 33, 37, 5391-94(1992).Catalytic asymmetric synthesis of substituted benzocycloalkenes via the glyoxylate ene reaction: Van der Meer F.T. etal.; Tetrahedron Lett. 33, 44, 6695-96 (1992).New homochiral binaphthol-modified organolanthanide reagents for the enantioselective addition to aldehydes: ChibaleK. et al.; Tetrahedron, Asymmetry 4, 12, 2407-2410 (1993).
Handling Instruction	Store in a tightly sealed container. Keep in a cool dry place away from heat and direct sunlight. Ensure good ventilation at the workplace.

Signal Word	Danger
Hazard Codes	H301-H315-H319-H335
Hazard Statements	Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Codes	P280H-P305+P351+P338-P309-P310
Precautionary Statements	Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
Risk Codes	25-36/37/38
Risk Phrases	Toxic if swallowed. Irritating to eyes, respiratory system and skin.
Safety Codes	26-36/37-45
Safety Phrases	In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
WGK Germany	3
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
TSCA	No
RTECS	DU3106100

Products specifications

Common name	(R)-(+)-BINOL
Assay	99%
CAS #	18531-94-7
MDL #	MFCD00004068
Molecular Formula	C20H14O2
Molecular Weight	286.32
Beilstein	3616837.00
Reaxys-RN	997518.00
UN#	UN2811
Harmonized Tariff Code	2907.29
Appearance	white to off-white solid
Melting Point	208-210 °C
Density	1.30
[α]D	+36.0° (c=0.5, THF)
Reference	The (R)- and (S)-isomers are useful for the preparation of chiral reducing agents, crown ethers, organotitaniumreagents and hydroboration catalysts. For references, see Aldrichimica Acta, 16(1), 14 (1983). Catalytic asymmetric oxidation of sulfides to sulfoxides using R-(+)-binaphthol: N. Komatsu et al.; Tetrahedron Lett. 33, 37, 5391-94(1992).Catalytic asymmetric synthesis of substituted benzocycloalkenes via the glyoxylate ene reaction: Van der Meer F.T. etal.; Tetrahedron Lett. 33, 44, 6695-96 (1992).New homochiral binaphthol-modified organolanthanide reagents for the enantioselective addition to aldehydes: ChibaleK. et al.; Tetrahedron, Asymmetry 4, 12, 2407-2410 (1993).
Handling Instruction	Store in a tightly sealed container. Keep in a cool dry place away from heat and direct sunlight. Ensure good ventilation at the workplace.