300683

(1,​5-​Cyclooctadiene)​bis[(trimethylsilyl)​methyl]​palladium, 98%

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Products specifications
Common name Pd(cod)(CH2TMS)2
Assay 98%
CAS # 225931-80-6
Molecular Formula C16H34PdSi2
Molecular Weight 389.03
Appearance gray pwdr.
Application Novel Pd complex for synthesis of allylsilanes via the Silyl-Heck reaction and aryl fluorides.
Reference McAtee, J. R. et al. J. Am. Chem. Soc. 2014, 136, 10166; Lee, H. G. et al. J. Am. Chem. Soc. 2014, 136, 3792; Watson, D. A. et al. Science 2009, 325, 1661.
Storage Temperature 0-4 °C
Handling Instruction Store in a tightly sealed container under an inert atmosphere. Keep in a cool dry place away from heat and direct sunlight. Ensure good ventilation at the workplace.
Signal WordWarning
Hazard CodesH315-H319-H335
Hazard StatementsCauses skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary CodesP261-P305+P351+P338
Precautionary StatementsAvoid breathing dust/fume/gas/mist/vapours/spray. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Risk Codes36/38
Risk PhrasesIrritating to the eyes. Irritating to the skin.
Safety Codes22-24/25-37/39-26
Safety PhrasesDo not breathe dust. Avoid contact with skin. Avoid contact with eyes. Wear suitable gloves. Wear eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany3
Personal Protective EquipmentEyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
TSCANo
Products specifications
Common name Pd(cod)(CH2TMS)2
Assay 98%
CAS # 225931-80-6
Molecular Formula C16H34PdSi2
Molecular Weight 389.03
Appearance gray pwdr.
Application Novel Pd complex for synthesis of allylsilanes via the Silyl-Heck reaction and aryl fluorides.
Reference McAtee, J. R. et al. J. Am. Chem. Soc. 2014, 136, 10166; Lee, H. G. et al. J. Am. Chem. Soc. 2014, 136, 3792; Watson, D. A. et al. Science 2009, 325, 1661.
Storage Temperature 0-4 °C
Handling Instruction Store in a tightly sealed container under an inert atmosphere. Keep in a cool dry place away from heat and direct sunlight. Ensure good ventilation at the workplace.
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