300690

1,2-Bis(phenylsulfinyl)ethane palladium(II) acetate, 98%

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Products specifications
Common name White Catalyst
Assay 98%
CAS # 858971-43-4
MDL # MFCD09842752
Molecular Formula C18H20O6PdS2
Molecular Weight 502.90
Appearance orange to brown pwdr.
Application Efficient bis-sulfoxide-Pd(II) catalyst for intramolecular allylic C–H oxidation, sequential allylic C–H oxidation/vinylic C–H arylation, and allylic C–H amination.
Reference White, M. C. et al. J. Am. Chem. Soc. 2014, 136, 10834; White, M. C. et al. J. Am. Chem. Soc. 2007, 129, 7274; White, M. C. et al. J. Am. Chem. Soc. 2006, 128, 15076; White, M. C. et al. J. Am. Chem. Soc. 2006, 128, 9032. Chen, M. S. et al. J. Am. Chem. Soc. 2005, 127, 6970.
Storage Temperature -20 °C
Handling Instruction Store in a tightly sealed container. Keep in a cool dry place away from heat and direct sunlight. Ensure good ventilation at the workplace.
Signal WordDanger
Hazard CodesH318
Hazard StatementsCauses serious eye damage.
Precautionary CodesP280-P305+P351+P338
Precautionary StatementsWear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Risk Codes41
Risk PhrasesRisk of serious damage to eyes.
Safety Codes26-39
Safety PhrasesIn case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection.
WGK Germany3
Personal Protective Equipmentdust mask type N95 (US), Eyeshields, Gloves
TSCANo
Products specifications
Common name White Catalyst
Assay 98%
CAS # 858971-43-4
MDL # MFCD09842752
Molecular Formula C18H20O6PdS2
Molecular Weight 502.90
Appearance orange to brown pwdr.
Application Efficient bis-sulfoxide-Pd(II) catalyst for intramolecular allylic C–H oxidation, sequential allylic C–H oxidation/vinylic C–H arylation, and allylic C–H amination.
Reference White, M. C. et al. J. Am. Chem. Soc. 2014, 136, 10834; White, M. C. et al. J. Am. Chem. Soc. 2007, 129, 7274; White, M. C. et al. J. Am. Chem. Soc. 2006, 128, 15076; White, M. C. et al. J. Am. Chem. Soc. 2006, 128, 9032. Chen, M. S. et al. J. Am. Chem. Soc. 2005, 127, 6970.
Storage Temperature -20 °C
Handling Instruction Store in a tightly sealed container. Keep in a cool dry place away from heat and direct sunlight. Ensure good ventilation at the workplace.